It is pointed out that carbonylation process in the presence of cobalt carbonyl is the most ideal one. 指出以羰基钴作为催化剂的羰基合成法为最理想的苯乙酸合成法。
Use the Chloride, sodium hydroxide and carbon monoxide as raw materials, taking the Cobalt Carbonyl as catalyst to produce Phenylacetate. 用氯苄、氢氧化钠和一氧化碳为原料,以羰基钴为催化剂生产苯乙酸。
Theoretical study on mononuclear and binuclear cobalt carbonyl nitrosyls 单核和双核钴羰基-亚硝基配合物的理论研究
Supported Metal Cluster ⅳ. Cobalt Carbonyl Cluster Supported on Polystyrene 担载金属簇Ⅳ.担载四核羰基钴簇的合成及醛化活性
Synthesis and Crystal Structure of Tetranuclear Cobalt Carbonyl Clusters 四核钴羰基簇合物的合成和晶体结构
Structure and Catalytic Properties of Cobalt and Iron Carbonyl Cluster-Time-of-Flight Mass Spectra and Quantum Chemistry Calculation 多核钴铁羰基簇结构与催化性能研究
Development in the Synthetic Method Of Cobalt Carbonyl and Relative Compounds 羰基钴及其盐的合成方法研究进展
For the first time, a cobalt carbonyl catalyst prepared under low pressure ( 12 atm) is applied to the process of preparing 1, 3-propanediol by hydroformylation of epoxide. 在低压下用雷尼镍及铁锰合金作还原剂合成四羰基钴催化剂,首次应用于羰基合成1,3-丙二醇中。
Carbonylation of Ethyl Chloroacetate Catalyzed by Cobalt Carbonyl 羰基钴催化羰化合成丙二酸二乙酯
Theoretical Studies on the Reductive Elimination of RCOCo ( H) 2 ( CO), in the Hydroformylation of Olefins with Cobalt Carbonyl as Catalyst 羰基钴催化烯烃醛化反应中RCOCo(H)2(CO)3还原消去关键步骤的理论研究
The technology of low pressure synthesis of tetracarbonyl cobalt with cobalt chloride and sulfur compounds with low valency has been used in the production of phenylacetic acid by carbonyl synthesis with benzyl chloride. 应用氯化钴和低价含硫化合物低压合成四羰基钴盐的技术于氯苄羰化合成苯乙酸的生产中。
At present, homogeneous cobalt carbonyl or its phosphine complex is used as the catalyst in the hydroformylation plants of higher olefins, even though the difficult separation and recovery of the cobalt catalyst is still a problem. 目前,高碳烯烃氢甲酰化主要采用均相的羰基钴或膦改性羰基钴为催化剂,存在钻催化剂分离和回收困难的问题。